Silver bromate

Silver bromate (AgBrO3), is a toxic, light and heat-sensitive, white powder.[2]

Silver bromate
Names
Systematic IUPAC name
Silver(I) bromate(V)
Other names
Argentous bromate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.120
  • InChI=1S/Ag.BrHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1 Y
    Key: XQLMNMQWVCXIKR-UHFFFAOYSA-M Y
  • InChI=1/Ag.BrHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
    Key: XQLMNMQWVCXIKR-REWHXWOFAZ
  • [Ag+].[O-]Br(=O)=O
Properties
AgBrO3
Molar mass 235.770 g/mol
Appearance white powder
photosensitive
Density 5.206 g/cm3
Melting point 309 °C (588 °F; 582 K)
0.167 g/100 mL
5.38×10−5[1]
Solubility in ammonium hydroxide soluble
Hazards
Safety data sheet (SDS) MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
Silver bromide GIF

Uses

Silver bromate can be used as an oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds.[3]

References
  1. John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 1138561630.
  2. Perry, Dale L. (2011). Handbook of inorganic compounds (2nd ed.). Boca Raton: Taylor & Francis. p. 365. ISBN 978-1-4398-1461-1. OCLC 587104373.
  3. Mohammadpoor-Baltork, Iraj; Nourozi, Ali Reza (1999). "Efficient and Selective Oxidative Deprotection of Tetrahydropyranyl Ethers, Ethylene Acetals and Ketals with Silver and Sodium Bromates in the Presence of Aluminum Chloride". Synthesis. 1999 (3): 487–490. doi:10.1055/s-1999-3410.


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